The forces and stresses are converged to 10 −3 a.u. In all calculations, complete relaxation of both forces and stress is required. The band gap calculation with the B3LYP 10 and PBE0 11 exchange-correlation functionals was performed with a norm-conserving pseudopotential and an energy cutoff of 80 Ry. The plane-wave expansion cutoff energies are 40 Ry and 200 Ry for wavefunctions and for density and potential, respectively. The numerical parameters were chosen to converge the energy to 10 −4 Ry per atom. The exchange-correlation functional is approximated by the Perdew-Burke-Ernzerhof (PBE) general gradient approximation 8.ĭensity-functional-perturbation-theory was employed for phonon calculations 9. The pseudopotential is from the Garrity, Bennett, Rabe, and Vanderbilt data set 7. The calculations were performed within the plane-wave formulation of density-functional theory (DFT) with ultra-soft pseudopotentials as implemented in the Quantum-Espresso simulation package 6. In this study, we employ ab initio methods to examine the mechanical and energetic stability, atomic structure, phonon dispersion curve, and band structure of graphullerene. The role of Mg atoms in stabilizing the structure and their effect on the material properties remain to be determined. A computational study of graphullerene in the absence of Mg was reported 5, indicating that the material is meta-stable. Specifically, its structure was deduced indirectly, while its electronic properties have only been probed. This two-dimensional structure has been termed graphullerene, and its corresponding three-dimensional van der Waals crystal, graphullerite 3.Īlthough graphullerene has been synthesized, it has only been partially characterized. Thus, some carbon atoms in this configuration are in sp 2, and others in sp 3 hybridization states. In this crystal, some of the carbon atoms bond with three nearest neighbors, and some, those that connect two neighboring molecules, have four nearest neighbor bonds. Subsequently, it was shown that the magnesium atoms of this two-dimensional crystal could be removed to form a pure allotrope of carbon with a C 60 molecule occupying each hexagonal lattice point 3. Recently, C 60 molecules were synthesized with magnesium to create a monolayer of a two-dimensional hexagonal periodic structure (Mg 4C 60) n 3, 4. The carbon ball consists of hexagons and pentagons of carbon atoms, such that each atom bonds to its three nearest neighbors 2 in an sp 2 hybridization. The C 60 molecule is a carbon ball similar in shape to a football, with an atom in each corner. However, although carbon is similar to silicon and germanium in its chemical bonding and electronic structure, none of the common allotropes of carbon, diamond, graphite or graphene are semiconductors. The recognition that the layered structure of graphite could be cleaved to form a two-dimensional carbon allotrope, graphene, was a significant development in condensed matter physics 1. In contrast, graphite is a layered structure characterized by an sp 2 hybridization between each atom and its three nearest neighbors in a given layer and van der Waals interactions between layers. Diamond is a three-dimensional network of carbon atoms each atom bonds with its four nearest neighbors within sp 3 hybridization. As a pure element, carbon has two well-known, extended allotropes: graphite and diamond, each with distinct properties. It can bond within molecules in different electronic configurations: sp, sp 2, and sp 3. Similar content being viewed by othersĬarbon is one of the essential elements in nature, as it participates in most of the complex organic structures that allow life. In addition, symmetry breaking of the C 60 molecules results in a distribution of bond lengths and creates vibrational modes that serve as a signature of graphullerene. Phonon spectrum calculations confirm the dynamical stability of the material and yield its in- and out-of-plane sound velocities. In the absence of Mg, this allotrope is a pure carbon semiconductor with an indirect band gap. However, the inclusion of Mg atoms transforms the cohesion energy from negative to positive values by forming additional C-Mg bonds, creating an energetically stable material. We find this structure to be meta-stable, owing to the strain produced by the covalent bonding of the molecules. Each of these molecules is connected to six neighbors in a hexagonal network with a total of eight chemical bonds. Structurally, graphullerene is composed of strained C 60 molecules. Ab initio calculations are employed to examine the structure and properties of this material. It has been synthesized in the form (C 60Mg 4) n and subsequently transformed into (C 60) n by removal of the Mg atoms. Graphullerene is a recently discovered, two-dimensional allotrope of carbon formed from C 60 molecules.
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Many iPhone and iPad users look no further than Apple Books for their reading needs as it’s the default app that comes with their Apple devices. Sounds like a lot? Well, it can be - but if you understood all that, or want to test it out, this is a great app. This app gives your phone an unlimited shutter speed - so you can take long star trail pictures or pictures of car lights zooming past, and it can even take a batch of photos with its intervalometer mode. If you want to take light-trail photography, pictures of the stars, or anything that needs a longer exposure time, Slow Shutter Cam should be your first stop. One of those is shutter speed, as you can’t take long exposures without the ability to fiddle with your shutter speed. It’s also highly customizable, so you can change the comment thread theme, overall app theme, and even the app icon to one of many amazing contributions from the Reddit community and popular designers.Īn iPhone camera is generally excellent, but it does lack some tools more advanced users would deem essential. It’s intuitive with a gesture-based interface, a fantastic media viewer for photos and video, a much easier-to-follow comments view, and more. Best of all, there are no ads to deal with. Apollo serves up all of your Reddit needs, from the front page to your subscribed subreddits, in a clean, no-frills interface. If you aren’t a fan of Reddit’s own app, then you should check out Apollo by Christian Selig. IOS Apollo Christine Romero-Chan / Digital Trends Just subscribe to the subreddits you want to hear from, unsubscribe from the rest, and Reddit will help to keep you fully updated with the latest news and interesting discussions. Especially good if you’re a fan of a wide variety of interests, Reddit’s front page can keep you up-to-date with everything you care about, from /r/worldnews, /r/android, and even /r/pokemon. It gets something of a bad rap due to certain bad apples, but Reddit is still an excellent place to gather news. But it’s not the only news app around, and there are plenty of other options if you want something more specialized or a different pace of news. There’s a lot of flexibility with what you can do in Marvis Pro versus the standard Music app, and this is a great way to rediscover those albums that you haven’t listened to in years.Īpple News is the default news app for iOS, and it’s a great news app. With Marvis Pro, you can access your entire Apple Music library, search for and add new music from the Apple Music catalog, rediscover forgotten albums in your collection, scrobble to Last.fm, and so much more. Marvis Pro is a highly customizable music app for those who use Apple Music but hate the default Apple Music interface. IOS Marvis Pro ($9) Christine Romero-Chan / Digital Trends You can listen to full albums and create playlists. It’s free on PCs and tablets, but $10 a month if you want to fully use it on iPhone. Spotify is changing the game for the entire music industry. Whether you’re there to watch some professional gamers play new decks on Hearthstone or a League of Legends tournament, the Twitch app allows you to chat with streamers and other viewers and watch previously recorded videos, and it’s AirPlay and Chromecast compatible. Yes, it sounds like the app version of being a younger sibling, but we promise you that it’s maddeningly compulsive once you get started. Twitch is the best place to watch other people play video games or professional tournaments, or just chill out with some real-life board games. IOS Twitch Image used with permission by copyright holder Not sure what Roblox involves? Check out our guide on Roblox to find out. Join your friends and explore thousands of different experiences created by people around the world. Roblox is less a game itself these days and more a platform for creative people to make their own games. Why is Roblox here and not in the best iOS games article? It’s because it’s one of the best apps to download to play a huge variety of games. IOS Gaming Roblox Image used with permission by copyright holder Never lose a great recipe again, thanks to Whisk. There’s a meal planner you can use to plan the week ahead, and making a shopping list is as easy as pressing a single button. Instead of that, why not start using Whisk? Whisk allows you to pool recipes from all over the internet, substitute ingredients and amounts, and basically create your very own cookbook. There are amazing free recipes everywhere on the internet - but finding the one you need is very much like dealing with a needle in a haystack, and it’s easy to lose a great recipe. It’s not contrast stitched like the LTZ’s perforated leather upholstery that gets sporty red thread around the inside of the seat bolsters and across the headrests, but rather more like those seats’ outer stitching and that on the leather-clad steering wheel. Of course, the next-gen Equinox will no doubt soften up much of its cabin and therefore GM’s argument will change in favor of premium surfaces, but at least this is an alternative take on the current entry-level luxury trend of softening as many contact areas as possible.Īs it is you’ll be hard pressed to find any soft touch plastics inside the Equinox, with the only pampering being door-mounted armrests that get a harder rubberized treatment with faux side stitching, plus a much more padded center armrest that’s covered in nicer leatherette stitched together with real thread in the French style. In truth hard plastic marks as easily as softer surfaces, but it doesn’t get pulled out of shape from sharp objects or worse, rip and tear, which means a tough and rigid interior like the Equinox’ may look better over time. I prefer to be kind and call its rugged plastic interior utilitarian, seemingly capable of taking on the most destructive of little league teams and coming out unscathed. Somehow GM missed a beat when it came time to upgrade its once class-leading Equinox and GMC Terrain cousin, and therefore it’s now a step or two behind in some respects. Now, volume brands are vying for premium buyers with luxuriously equipped and richly finished compact SUVs, whereas premium brands are trying to attract lower end buyers with ever smaller, more approachable models.Īlso notable, compact crossover SUV sales are encroaching on our once seemingly impenetrable mid-size car segment and the 13 models on offer are extremely competitive, some, as mentioned, more luxuriously appointed than many premium branded alternatives. I was on the initial press launch and was very impressed, even lauding on accolades like, “The new Equinox comes pretty close to replicating premium levels of interior quality, with attractive aluminum-like accents, soft-touch materials on the armrests, door inserts and really nicely finished harder touch plastics everywhere else.” OK, maybe I was somewhat overenthusiastic in referencing premium quality, but we need to remember that this was almost seven years ago and both the mainstream and premium markets have changed dramatically since then. To Chevy’s credit the Equinox came with a stylish interior featuring advanced electronics when it debuted in the summer of 2009 as a 2010 model. It will need to be standing still to appreciate its new range of wheels, the machine-finished twinned five-spoke 18-inch alloys on my top-line tester managing to look both sporty and elegant simultaneously. A new set of restyled DRLs enhance the Equinox’ modified lower front corners, upgraded to LEDs in top trims, while my LTZ’s halogen fog lamps are new too, but anyone catching the SUV’s profile passing by won’t likely see any changes unless they catch sight of the revised taillights that get stylish new lenses. That familiar bisected grille gets a couple of untraveled twists and turns, as do the headlights that come standard with halogen projector innards. The reworked grille and front fascia combination falls into the category of not necessarily better, just new, but that should suffice for many of the model’s faithful who are looking for a good excuse to upgrade. Just the same there are plenty of reasons to buck up for this refreshed 2016.įirst off, it still looks quite nice. Still, I’m sure those inside the hallowed halls of GM’s downtown Detroit HQ, the many more working across the nation in the General’s umpteen independent dealerships and you, a potential Equinox buyer, are looking forward to the aforementioned redesign. Despite its age sales grew by 14.6 percent last year, following a general upward trend in the compact SUV segment. I liked the styling of the first-gen version too, all 12 years of Equinox sales adding up to 1,929,897 as of February. The design team didn’t stray too far from the second-generation model that’s sold very well for the bowtie brand. No, don’t get too excited, you’ll still have to wait about a year or so for a completely redesigned version, but Chevy has given the current model a nice mid-cycle makeover. !() Subtle refresh helps this older SUV keep up to fast-paced compact segment() While you ice cream mix is thickening melt your chocolate. Temper the egg yokes by adding the milk, about a third at a time, mixing well between each addition.Īdd the mix to the top of the double boiler and put onto a medium to low heat. Separate the egg yokes and put the whites aside for another recipe, such as my amaretti cookies and pretty rainbow meringues.Īdd the sugar to the egg yokes and mix with an electric mixer until pale and creamy. Put the milk into a small saucepan on a low to medium heat to warm up. If using a double boiler, put the water onto boil. Measure carefully, preferably using a digital kitchen scale, and don't add to much or your ice cream will melt in a red hot minute! How to make rocky road ice cream You can substitute with the same amount of light corn syrup or powdered dextrose. A small amount of glucose syrup helps lower the freezer point of ice cream and improves the texture and scoop-ability of the ice cream. You can get in from specialty baking shops, online and some supermarkets. Glucose syrup (optional): also called confectioner’s glucose. You could also use heavy cream or heavy whipping cream which is similar. Thickened cream: I use thickened cream in Australia which as a fat content of about 34%. I don't recommend using low fat milk, it will make your ice cream icier. It needs to have a fat content of around 3.5%. Ingredientsįull fat milk: is best for this recipe. Or if you're in the mood for more delectable ice cream check out my full collection of Cuisinart ice cream maker recipes (that work well in other brands ice cream makers too!). Looking for more fabulous nutty ice creams? Why not try making my beautiful green pistachio ice cream (that actually tastes like pistachios), chunkey money ice cream with chunks of roasted walnuts or easy peanut butter ice cream. I like to throw in some soft raspberry lollies or candy for some extra color and flavor but you can use whatever soft candies you like, or leave them out altogether. This recipe starts with a delicious milk chocolate ice cream and adds the classic rocky road flavors of marshmallows and almonds. So it made sense to turn this easy dessert into a delicious ice cream. It's always a hit when I make it for bake sales. It's perfect to whip up when you don't have time to bake and I usually have the ingredients I need in the pantry. If it’s summertime, they will be best stored in the fridge and can last up to 2 weeks, if not longer! When placing them in your container add baking paper in between the layers to prevent them from sticking together.Rocky road is my favorite no bake dessert. Keep your rocky roads in a cool place and store them in an air-tight container. Chill for at least 2 hours, dust with icing sugar, and cut into squares. If you want a thicker rocky road, just use one tin. Tip into the tins and spread out into the corners.Add the rest of the ingredients to the saucepan and stir until everything is covered.Melt the butter, chocolate and syrup in a saucepan over gentle heat.Bash the biscuits in a bag, so there are lots of little chunks of biscuits.This will make it easier for you to pull out of the tin. Grease and fully line your baking tins with baking paper.Icing Sugar to dust How to make Rocky Roads.When measuring your golden syrup, rub the tablespoon with some oil. You could also add Maltesers! Just half the quantity of digestive biscuits and add the same amount of Maltesers. You could even add glace cherries for extra sweetness and colour!Ĭhange the biscuits to a different variety like bourbons or biscoffsĬhange the dark chocolate to milk if dark chocolate is not to your liking.įull recipe at the bottom of this post.
Or, use the Uninstall or change a program section in the Control Panel. Use the standard control panel utilities for your system to find and remove the Unreal Datasmith Exporter for Rhino application.įor example, on Windows 10, you can use the Apps & Features section of the Control Panel:Ĭlick the entry for your Datasmith Exporter plugin in the list, then click Uninstall. See Exporting Datasmith Content from Rhino. With the Datasmith Exporter plugin installed, you can now export scenes from Rhino as a. Check the box for each version you want to use to be able to export to Datasmith, and click Install. The installer automatically detects which versions of Rhino are installed on your system. When the download is complete, navigate to the location of the file and run the installer.įollow the on-screen instructions and accept the license agreement to continue. For details, see Removing the Datasmith Exporter for Rhino on this page.ĭownload the Exporter plugin installer from the Datasmith Exporter Plugins download page. If you already have an older version of the Datasmith Exporter plugin, we recommend uninstalling it first before proceeding. If any instances are currently running on your machine, the installation will fail. Installing the Datasmith Exporter for Rhino Follow the steps below to install the Datasmith Exporter plugin for any supported version of Rhino that you have installed on your computer:Ĭlose any running instances of Rhino on your machine. Please note that you are not permitted to distribute the Datasmith Exporter plugins themselves. We encourage you to share the download link to the Datasmith Exporter plugins with any number of people, both inside and outside of your organization. To see what versions of Rhino the plugin supports, see Datasmith Supported Software and File Types. Removing the Datasmith Exporter for Rhinoīefore you can begin exporting your Rhino content to Unreal Engine 4, you will need to install the Unreal Datasmith Exporter for Rhino. Installing the Datasmith Exporter for Rhino No maintenance fees.How to install the Datasmith Exporter for Rhino Fast, even on an ordinary laptop computer.It is so easy to learn and use that you can focus on design and visualization without being distracted by the software. Read and repair meshes and extremely challenging IGES files.
Macy’s however, appears to be going all out to make the stores, not just the flagships, a success. Visitors to non-flagship locations could be disappointed if they find only a small assortment of toys located in an out-of-the way, dimly-lit corner of the store. “The flagship stores look very, very good,” Zahn said, and “give a hint of what the partnership could become.” However, he said, “the consumer experience varies widely at the different Macy’s stores.” All of the Toys R Us branded locations will have Toys R Us signage and images, and a bench with a Geoffrey figure sitting on it for photos. Outside of the flagship locations, however, the Toys R Us shops could be as small as 1,000 square feet. It also has various tables stocked with toys kids can play with, and spaces for special activities. The Herald Square location is the largest of the shops, at 14,000 square feet, and has photo-opp features like a New York City taxi with a Geoffrey statue as a passenger, and a replica of the Macy’s Thanksgiving parade made out of Legos. The Herald Square Toys R Us is one of 11 flagship toy shops at Macy’s stores. Gennette has said repeatedly since embarking on the Toys R Us partnership that Macy’s believes that although a lot of toy sales shifted to the big three toy sellers - Walmart WMT, Target, and Amazon AMZN - after the demise of the old Toys R Us, that there still is a billion dollar’s worth of toy opportunity up for grabs. James Zahn, editor-in-chief of The Toy Book, said he has been hearing that the stores that opened the new toy departments earlier are already seeing a lift in sales in adjacent departments, such as kids clothing. While the official launch of the in-store shops didn’t take place until last week, Macy’s has been setting up the toy displays for several months, and the cross-shopping boost also appears to be occurring in stores in the same way it has been happening online. In the first quarter of 2022, 87% of toy customers also cross-shopped other Macy’s categories. In the fourth quarter of 2021, 25% of Macy’s online customers who bought toys under the Toys R Us partnership were new to the Macy’s site. (Photo by Eugene Gologursky/Getty Images for Macy's, Inc.) Getty Images Children playing with Play Doh at the grand opening of the Toys R Us shop at Macy's Herald Square.
Constitution is a trap, except potentially for a couple points to carry a shield if you want one. Just pouring tons of points into Intelligence and Wits, with some memory for spells, is the way to go. His Time Warp ability allows him to set up spell combinations even more nicely than usual, which is quite nice if you've got Source to spare. I personally enjoy playing Fane as an elemental wizard, either pyro/geo or aero/hydro. Elves make notably better necromancers due to flesh sacrifice, but otherwise everybody can do everything more or less equally.Ĭonsider giving Fane your thievery points, though, as his bone fingers means that you'll never need lockpicks. As most of the healing you will recieve will be through necromancy, the more damage you deal, the more you will heal through necromancy, the more magic armor will you regenerate through living armor. I also don't really follow that being a particularly effective "combo", as Necromancy requires Warfare points to properly scale up, and deals physical damage, making it not work especially well alongside Geomancy. Necro for example gives you life steal, healing you for a percent of damage dealt. Vendor Prices, Bartering & Attitude FormulaĪny character can be anything, so I wouldn't say Fane is any better a necro/geo than anybody else. Level Up: Attribute, Skill & Talent Point Breakdown They get spell scaling so they don't have to worry about upgrading weapons, and can use weapons purely for the stats. Because necromancers do physical damage, they don't have to worry about resistances. The Quick Questions and Looking for Group Threads exist for a reason, use them. Necromancer has all the benefits of physical damage, spell scaling, and insane damage. So my plan was to play with ivan and Lohse, since they are the only interesting characters i did not play with, so i wanted to try lone wolfing with them. (Also want to try tactician but not now lol). >!This is spoilery!< to get This is spoilery So there are a few things i want to try now: a summoner, a rogue-poly, a int-necro build and lone wolf. Submissions should relate to Divinity Original Sin or other works of Larian Studios.ĭo not put spoilers in the title of your post and mark your posts. Join up with a friend to play online in co-op and make your own adventures with the powerful RPG toolkit. Gather your party and get ready for a new, back-to-the-roots RPG adventure! Discuss your decisions with companions fight foes in turn-based combat explore an open world and interact with everything and everyone you see. Welcome To The Divinity: Original Sin Subreddit! Looking for a Group to play with? Try this thread || Discussion Overview Fixed Time Entry Editor popover not closing on click outside after changing the Time Entry’s task.Save notes after adding/editing them in the dashboard window and then switch to another application. Resolved rendering issues in macOS Sonoma.Addressed some German localization issues. Fixed a critical bug that could cause the app to crash on launch.Added a shortcut (CMD+K) to quickly edit current time entry notes in the dashboard window.Prevent start/pause buttons from being pressed by Bartender while hiding/showing items in the menu bar. The full Timeular experience on any operating system.Harvest for Windows makes it easy to track time and review your tracked hours for the week without interrupting your workflow. Enhanced Auto-tracking support for Affinity products. Join 70,000+ companies spending their time wisely with Harvest.Time entry list: Begin and end times have been swapped for smoother scanning from top to bottom.Added Auto-tracking support for Whale Browser.Dashboard window: Search for folder names effortlessly.Its automation features are of particular interest, as they can save you a lot of effort. Input values like “50 min,” “2h 23m,” or simply “2”. Overall, this app can make a big difference for freelancers who struggle with tracking their work hours and calculating revenue efficiently. Time entry duration can now be edited directly.Just tell Timemator what files, applications or websites you use for your work and it will start the timer for you. These Unix tools can be compiled for a variety of Unix platforms, including Linux. Joe brings that same passion to How-To Geek.Timemator lets you fully automate your time-tracking based on your activities on the Mac. Version 12 of the Unix LC-3 simulator is available here. If something piques his interest, he will dive into it headfirst and try to learn as much as possible. THREE NEW FEATURES were added: absence request, fire roll call and geofencing. This improved version of the TimeMoto app enables your employees to clock in. Outside of technology, Joe is an avid DIYer, runner, and food enthusiast. Easy, accurate mobile clocking and attendance management powered by the. After several years of jailbreaking and heavily modifying an iPod Touch, he moved on to his first smartphone, the HTC DROID Eris. Save time on administration by using TM time tracking software. He got his start in the industry covering Windows Phone on a small blog, and later moved to Phandroid where he covered Android news, reviewed devices, wrote tutorials, created YouTube videos, and hosted a podcast.įrom smartphones to Bluetooth earbuds to Z-Wave switches, Joe is interested in all kinds of technology. Information about the Cloud Plans, 3 year warranty and FCC compliance. He has written thousands of articles, hundreds of tutorials, and dozens of reviews.īefore joining How-To Geek, Joe worked at XDA-Developers as Managing Editor and covered news from the Google ecosystem. Joe loves all things technology and is also an avid DIYer at heart. Qui puoi trovare le schede tecniche e la guida rapida allinstallazione del TimeMoto PC Software. He has been covering Android and the rest of the Google ecosystem for years, reviewing devices, hosting podcasts, filming videos, and writing tutorials. Joe Fedewa has been writing about technology for over a decade. Github Push Error: OpenSSL SSL_connect: SSL_ERROR_SYSCALL in connection to github.Git pull code authentication failed with error: fatal: authentication failed for “XXXX”.In Azure DevOps you can then configure a set of Git Credentials or a Personal Access Token and use that to connect directly. I performed the above operation using https. To force the Git credential Manager to stop interfering, you can add the following to your global git config: credential helper This effectively turns off any credential manager. Git: How to Solve Authentication failed I get error like fatal: Authentication failed for.Next, a small window will pop up, prompting you to enter your password, enter your git password, and click OK Similar Posts: Then press enter, enter the URL of GIT clone copy, and then press enterĪt this time, the command line will appear asking for the user name, then enter your git user name and press enter Download and install gh here After installation, open vs code terminal and login to github with gh auth login. Its quite common that we save our credentials on our local machine so that we dont need to provide them each time we access our remote repository. The errors are as follows:įatal: Authentication failed for 'http:xxxx.git/''Īfter some Baidu found a solution, just input Configure VS Code Github authentication using Github CLI, gh. With this previous answer I was able to use git clone, etc using SSH on the problematic machine. When you enter the user name and password incorrectly in the clone on git, the window for entering the user name and password will no longer pop up automatically. |
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